Open Access Publications

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Open access publications by faculty, postdocs, and graduate students in the Department of Earth Sciences.

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An evolving database for Quaternary aminostratigraphy
(GeoResJ, 2015-03-27) Wehmiller, John F.; Pellerito, Vincent
Amino acid racemization (AAR) dating methods have been used since the mid-1960s. Since that time, information technologies have evolved as AAR laboratories have worked to appropriately catalog sample collections and analyses. The University of Delaware AAR Database (UDAARDB) is a database of AAR and other geochronological data from coastal Quaternary sites in North and South America that has been in development for over 25 years. In that time, database and software platforms have changed and a concerted effort has been made to digitize legacy data for preservation and to make these data available for future use. To ensure data preservation, all or part of UDAARDB is redundantly hosted at three institutions as data files and maps. Furthermore, the flexible nature of accessing the data (i.e., as online maps and common format data files) helps to maintain a public presence and, therefore, assists in their preservation.
The Taitao Ophiolite: Snapshot of Nascent Oceanic Mantle Emplaced Via Ridge-Trench Collision
(Journal of Petrology, 2025-10-23) Lin, Kuan-Yu; Warren, Jessica M; Schilling, Manuel E; Plissart, Gaëlle; Corgne, Alexandre; Akizawa, Norikatsu; Anma, Ryo; Alvear, Maite; González, Emilio; Marin, Catalina
The Taitao ophiolite is a sliver of oceanic lithosphere that formed at the Chile ridge at ~6 Ma and was emplaced shortly afterwards onto the Chilean continental margin during a ridge-trench collision. Located southeast of the modern-day Chile Triple Junction, the ophiolite provides a unique window into the mantle beneath an intermediate-spreading ridge axis, from which few peridotites have been recovered globally. We analyzed the compositions of harzburgites, plagioclase harzburgites, and clinopyroxenites from the mantle section of the Taitao ophiolite to investigate the history of partial melting, melt addition, and thermal evolution. Most Taitao harzburgites have spinel major element and clinopyroxene rare earth element contents that are consistent with residues after 12–15% melting of a depleted MORB mantle source. The compositional modifications due to melt addition are generally limited and spatially confined to plagioclase harzburgites near gabbroic intrusions and clinopyroxenites associated with dunites. To constrain the thermal history of the Taitao ophiolite from formation at the Chile ridge to emplacement at the Chilean continental margin, we calculated closure temperatures by applying pyroxene- and olivine-based geothermometry to the Taitao peridotites. We compare these results with models for closure temperature as a function of initial temperature and cooling rate. Our results suggest that the Taitao peridotites underwent faster cooling (1–10°C/yr) than ophiolites globally, most of which cooled with rates <1°C/yr. This agrees with our calculation that the peridotites remained at high temperature for a relatively short time (<0.5 My) based on timescale estimates of emplacement using a ridge thermal model and mineral diffusive re-equilibration. Our rapid cooling rates for the Taitao peridotites exceed predictions from conductive cooling models, even those that account for hydrothermal effects, indicating the involvement of additional mechanisms. We interpret the fast cooling to result from ridge-trench collision and rapid obduction. This tectonic configuration juxtaposed hot sub-ridge mantle against a cold continental margin, leading to a significant temperature contrast and, therefore, faster average cooling rates during ophiolite emplacement. Other ophiolitic peridotites, in contrast, typically remain part of the oceanic lithosphere for longer and experience prolonged conductive cooling prior to obduction, resulting in slower cooling rates. Altogether, our results demonstrate that the Taitao ophiolite is an ideal archive for studying tectonic processes at intermediate-spreading ridges and during ridge-trench collision.
Molluscan aminostratigraphy of the US Mid-Atlantic Quaternary coastal system: Implications for onshore-offshore correlation, paleochannel and barrier island evolution, and local late Quaternary sea-level history
(Quaternary Geochronology, 2021-05-18) Wehmiller, John F.; Brothers, Laura L.; Ramsey, Kelvin W.; Foster, David S.; Mattheus, C.R.; Hein, Christopher J.; Shawler, Justin L.
The Quaternary record of the US Mid-Atlantic coastal system includes onshore emergent late Pleistocene shoreline deposits, offshore inner shelf and barrier island units, and paleovalleys formed during multiple glacial stage sea-level lowstands. The geochronology of this coastal system is based on uranium series, radiocarbon, amino acid racemization (AAR), and optically stimulated luminescence (OSL) methods. We report over 600 mollusk AAR results from 93 sites between northeastern North Carolina and the central New Jersey shelf, representing samples from both onshore cores or outcrops, sub-barrier and offshore cores, and transported shells from barrier island beaches. AAR age estimates are constrained by paired 14C analyses on specific shells and associated U-series coral ages from onshore sites. AAR data from offshore cores are interpreted in the context of detailed seismic stratigraphy. The distribution of Pleistocene-age shells on the island beaches is linked to the distribution of inner shelf or sub-barrier source units. Age mixing over a range of time-scales (~1 ka to ~100 ka) is identified by AAR results from onshore, beach, and shelf collections, often contributing insights into the processes forming individual barrier islands. The regional aminostratigraphic framework identifies a widespread late Pleistocene (Marine Isotope Stage 5) aminozone, with isolated records of middle and early Pleistocene deposition. AAR results provide age estimates for the timing of formation of the three major paleochannels that underlie the Delmarva Peninsula: Persimmon Point paleochannel ≥800 ka; Exmore paleochannel ~400–500 ka (MIS 12); and Eastville paleochannel > 125 ka (MIS 6). The results demonstrate the value of synthesizing abundant AAR chronologic data across various coastal environments, integrating multiple distinct geologic studies. The ages and elevations of the Quaternary units are important for current hypotheses about relative sea-level history and crustal dynamics in the region, which was likely influenced by the Laurentide ice sheet, the margin just ~400 km to the north.
Structure of the Ecuadorian Upper Plate From a Joint Seismic‐Gravity Inversion
(Journal of Geophysical Research (JGR): Solid Earth, 2025-08-11) Birkey, Andrew; Lynner, Colton; Chai,Chengping; Maceira, Monica
The Ecuadorian portion of the South American subduction zone presents an interesting case study in the structure and complex evolution of an upper plate. There are outstanding questions about its tectonic history, composition, and magmatic processes. While previous studies have employed ambient noise tomography to image the Ecuadorian upper plate, surface wave inversions alone often lack sensitivity at relevant shallow depths. This limitation can be overcome with an independent, complementary data set, such as gravity. We have jointly inverted Rayleigh wave phase velocities and Bouguer gravity anomalies to provide a more detailed seismic velocity model of the Ecuadorian upper plate. Our joint inversion has yielded several key improvements from previous models. First, we observe much shallower slow velocities beneath major basins (the Manabí, Progreso, and Gulf of Guayaquil), better aligning with expected basin structure. Second, we identify a high‐velocity block beneath the entire forearc, corresponding to the Piñon Terrane, with velocities suggesting the presence of ultramafic material. Third, we highlight a new narrow swath of slow velocities beneath the Ecuadorian Andes, which closely follows the active volcanoes along the Eastern Cordillera. The extent of these slow velocities coincides with the termination of active arc volcanism and the predicted location of the subducted Carnegie Ridge. The predicted compositions for the mid to lower crust in the region preclude a purely compositional explanation for these velocities, suggesting that some level of partial melt is necessary.
Seismic imaging of the Ecuadorian forearc and arc from joint ambient noise, local, and teleseismic tomography: catching the Nazca slab in the act of flattening
(Geophysical Journal International, 2025-06-01) Rodríguez, E. E.; Beck, S. L.; Meltzer, A.; Segovia, M.; Ruíz, M.; Hernández, S.; Roecker, S.; Lynner, C.; Koch, C.; Hoskins, M. C.; Charvis, P.; Agurto-Detzel, H.; Rietbrock, A.; León-Ríos, S.
The Ecuadorian Andes are a complex region characterized by accreted oceanic terranes driven by the ongoing subduction of the oceanic Nazca plate beneath South America. Present-day tectonics in Ecuador are linked to the downgoing plate geometry featuring the subduction of the aseismic, oceanic Carnegie Ridge, which is currently entering the trench. Using seismic tomography, we jointly invert arrival times of P and S waves from local and teleseismic earthquakes with surface wave dispersion curves to image the structure of the forearc and magmatic arc of the Ecuadorian Andes. Our data set includes > 100 000 traveltimes recorded at 294 stations across Ecuador. Our images show the basement of the central forearc is composed of accreted oceanic terranes with high elastic wave speeds. Inboard of the Carnegie Ridge, the westernmost forearc and coastal cordilleras display relatively low Vp and Vs and high Vp/Vs values, which we attribute to the increased hydration and fracturing of the overriding plate due to the subduction of the thick oceanic crust of the Carnegie Ridge. We additionally image across-arc differences in magmatic architecture. The frontal volcanic arc overlies accreted terranes and is characterized by low velocities and high Vp/Vs indicative of partial melt reservoirs which are limited to the upper crust. In contrast, the main arc displays regions of partial melt across a wider range of depths. The Subandean zone of Ecuador has two active volcanoes built on continental crust suggesting the arc is expanding eastwards. The mid to lower crust does not show indications of being modified from the magmatic process. We infer that the slab is in the process of flattening as a consequence of early-stage subduction of the buoyant Carnegie Ridge.
A Perceptual Model of Drivers and Limiters of Coastal Groundwater Dynamics
(Hydrological Processes, 2025-01-27) Kretschmer, Daniel V.; Michael, Holly A.; Moosdorf, Nils; Oude Essink, Gualbert H. P.; Bierkens, Marc F. P.; Wagener, Thorsten; Reinecke, Robert
Coastal groundwater is a vital resource for coastal communities around the globe, and submarine groundwater discharge (SGD) delivers nutrients to coastal marine ecosystems. Climatic changes and anthropogenic actions alter coastal hydrology, causing seawater intrusion (SWI) globally. However, the selection of SWI and SGD study sites may be highly biased, limiting our process knowledge. Here, we analyse hydroenvironmental characteristics of coastal basins studied in 1298 publications on SGD and SWI to understand these potential biases. We find that studies are biased towards basins with gross domestic product per capita below (SWI) and above (SGD) the median of all global coastal basins. Urban coastal basins are strongly overrepresented compared to rural coastal basins, limiting our progress in understanding undisturbed natural processes. Despite the connection between anthropogenic activity and coastal groundwater issues, and the consequential overrepresentation of urban basins in coastal groundwater studies, perceptual (or conceptual) models of coastal groundwater rarely include anthropogenic influences aside from pumping (e.g., subsidence, land use change). Taking a holistic view on coastal groundwater flows, we have developed an editable perceptual model illustrating the current understanding, including both natural and anthropogenic drivers. As SGD and SWI in new areas of the globe are studied, we advocate for researchers to utilise and further edit this perceptual model to openly communicate our process understanding and study assumptions.
Living in Their Heyday: Iron-Oxidizing Bacteria Bloomed in Shallow-Marine, Subtidal Environments at ca. 1.88 Ga
(Geobiology, 2024-12-05) Kovalick, Alex; Heard, Andy W.; Johnson,, Aleisha C.; Chan, Clara S.; Ootes, Luke; Nielsen, Sune G.; Dauphas, Nicolas; Weber, Bodo; Bekker, Andrey
The majority of large iron formations (IFs) were deposited leading up to Earth's great oxidation episode (GOE). Following the GOE, IF deposition decreased for almost 500 Myr. Subsequently, around 1.88 Ga, there was widespread deposition of shallow-water granular iron formations (GIF) within a geologically short time interval, which has been linked to enhanced iron (Fe) supply to seawater from submarine hydrothermal venting associated with the emplacement of large igneous provinces. Previous studies of Fe-rich, microfossil-bearing stromatolites from the ca. 1.88 Ga Gunflint Formation on the Superior craton suggested direct microbial oxidation of seawater Fe2+(aq) by microaerophilic, Fe-oxidizing bacteria (FeOB), as a driver of GIF deposition. Although Fe-rich, microfossil-bearing stromatolites are common in 1.88 Ga GIF deposits on several cratons, combined paleontological and geochemical studies have been applied only to the Gunflint Formation. Here, we present new paleontological and geochemical observations for the ca. 1.89 Ga Gibraltar Formation GIFs from the East Arm of the Great Slave Lake, Northwest Territories, Canada. Fossil morphology, Rare Earth element (REE) concentrations, and Fe isotopic compositions support Fe oxidation by FeOB at a redoxcline poised above the fair-weather wave base. Small positive Eu anomalies and positive εNd (1.89 Ga) values suggest upwelling of deep, Fe-rich, hydrothermally influenced seawater. While high [Fe2+(aq)] combined with low atmospheric pO2 in the late Paleoproterozoic would have provided optimal conditions in shallow oceans for FeOB to precipitate Fe oxyhydroxide, these redox conditions were likely toxic to cyanobacteria. As long as local O2 production by cyanobacteria was strongly diminished, FeOB would have had to rely on an atmospheric O2 supply by diffusion to shallow seawater to oxidize Fe2+(aq). Using a 1-D reaction dispersion model, we calculate [O2(aq)] sufficient to deplete an upwelling Fe2+(aq) source. Our results for GIF deposition are consistent with late Paleoproterozoic pO2 estimates of ~1%–10% PAL and constraints for metabolic [O2(aq)] requirements for modern FeOB. Widespread GIF deposition at ca. 1.88 Ga appears to mark a temporally restricted episode of optimal biogeochemical conditions in Earth's history when increased hydrothermal Fe2+(aq) sourced from the deep oceans, in combination with low mid-Paleoproterozoic atmospheric pO2, globally satisfied FeOB metabolic Fe2+(aq) and O2(aq) requirements in shallow-marine subtidal environments above the fair-weather wave base.
Genome editing in ubiquitous freshwater Actinobacteria
(Applied and Environmental Microbiology, 2024-10-16) Bairagi, Nachiketa; Keffer, Jessica L.; Heydt, Jordan C.; Maresca, Julia A.
Development of genome-editing tools in diverse microbial species is an important step both in understanding the roles of those microbes in different environments, and in engineering microbes for a variety of applications. Freshwater-specific clades of Actinobacteria are ubiquitous and abundant in surface freshwaters worldwide. Here, we show that Rhodoluna lacicola and Aurantimicrobium photophilum, which represent widespread clades of freshwater Actinobacteria, are naturally transformable. We also show that gene inactivation via double homologous recombination and replacement of the target gene with antibiotic selection markers can be used in both strains, making them convenient and broadly accessible model organisms for freshwater systems. We further show that in both strains, the predicted phytoene synthase is the only phytoene synthase, and its inactivation prevents the synthesis of all pigments. The tools developed here enable targeted modification of the genomes of some of the most abundant microbes in freshwater communities. These genome-editing tools will enable hypothesis testing about the genetics and (eco)physiology of freshwater Actinobacteria and broaden the available model systems for engineering freshwater microbial communities. IMPORTANCE To advance bioproduction or bioremediation in large, unsupervised environmental systems such as ponds, wastewater lagoons, or groundwater systems, it will be necessary to develop diverse genetically amenable microbial model organisms. Although we already genetically modify a few key species, tools for engineering more microbial taxa, with different natural phenotypes, will enable us to genetically engineer multispecies consortia or even complex communities. Developing genetic tools for modifying freshwater bacteria is particularly important, as wastewater, production ponds or raceways, and contaminated surface water are all freshwater systems where microbial communities are already deployed to do work, and the outputs could potentially be enhanced by genetic modifications. Here, we demonstrate that common tools for genome editing can be used to inactivate specific genes in two representatives of a very widespread, environmentally relevant group of Actinobacteria. These Actinobacteria are found in almost all tested surface freshwater environments, where they co-occur with primary producers, and genome-editing tools in these species are thus a step on the way to engineering microbial consortia in freshwater environments.
Beyond the Wedge: Impact of Tidal Streams on Salinization of Groundwater in a Coastal Aquifer Stressed by Pumping and Sea-Level Rise
(Water Resources Research, 2024-09-27) Hingst, M. C.; Housego, R. M.; He, C.; Minsley, B. J.; Ball, L. B.; Michael, H. A.
Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume. Key Points - Presence of a saltmarsh inverts the freshwater-saltwater interface in our study location - Tidal streams contribute substantially to salinization of inland groundwater - Concentrated pumping led to more intensive salinization than widespread pumping
Clues on the Australasian impact crater site inferred from detailed mineralogical study of a monazite inclusion in a Muong Nong tektite
(Geology, 2024-09-04) Seydoux-Guillaume, A.-M.; Rochette, P.; Gardés, E.; Zanetta, P.-M.; Sao-Joao, S.; de Parseval, Ph.; Glass, B.P.
Tektites are terrestrial impact-generated glasses distributed over regions of Earth’s surface with ejection distances up to 10,000 km. The Australasian tektite strewn field is the largest and the youngest discovered so far (788 ka). However, the location of the source crater remains unsolved. The present work is the first to investigate the only monazite ever found as an inclusion in a Muong Nong tektite (MNT) from Indochina. In-depth observations down to the nanoscale revealed that the monazite experienced very high temperature, with silicate melt injection sometimes trapped within porosity at the grain boundaries, followed by a recovery mechanism responsible for dislocation migration and subgrain formation. The absence of radiation damage confirms that this recovery episode occurred recently, in line with the age of the tektite. The preservation of a primary zonation (Th component) and the absence of detectable diffusion profiles indicate that the monazite did not reach the melting point (∼2050 °C) before initial rapid cooling (∼1000 °C/s). The U-Th−total Pb dates of the monazite thus remained unchanged during the impact: 73 ± 6 Ma in a Th-rich domain and 156 ± 15 Ma in a Th-poor domain. This allows the source of the MNT to be constrained. Comparison with a detailed database of monazite ages and Th/U ratios in SE Asia indicates that the Australasian crater should be sought for in the triangle made up of the Philippines, coastal south China, and northern Vietnam, though the latter appears less probable.
Size-dependent effects of dams on river ecosystems and implications for dam removal outcomes
(Ecological Applications, 2024-08-13) Brown, Rebecca L.; Charles, Don; Horwitz, Richard J.; Pizzuto, James E.; Skalak, Katherine; Velinsky, David J.; Hart, David D.
Understanding the relationship between a dam's size and its ecological effects is important for prioritization of river restoration efforts based on dam removal. Although much is known about the effects of large storage dams, this information may not be applicable to small dams, which represent the vast majority of dams being considered for removal. To better understand how dam effects vary with size, we conducted a multidisciplinary study of the downstream effect of dams on a range of ecological characteristics including geomorphology, water chemistry, periphyton, riparian vegetation, benthic macroinvertebrates, and fish. We related dam size variables to the downstream–upstream fractional difference in measured ecological characteristics for 16 dams in the mid-Atlantic region ranging from 0.9 to 57 m high, with hydraulic residence times (HRTs) ranging from 30 min to 1.5 years. For a range of physical attributes, larger dams had larger effects. For example, the water surface width below dams was greater below large dams. By contrast, there was no effect of dam size on sediment grain size, though the fraction of fine-grained bed material was lower below dams independently of dam size. Larger dams tended to reduce water quality more, with decreased downstream dissolved oxygen and increased temperature. Larger dams decreased inorganic nutrients (N, P, Si), but increased particulate nutrients (N, P) in downstream reaches. Aquatic organisms tended to have greater dissimilarity in species composition below larger dams (for fish and periphyton), lower taxonomic diversity (for macroinvertebrates), and greater pollution tolerance (for periphyton and macroinvertebrates). Plants responded differently below large and small dams, with fewer invasive species below large dams, but more below small dams. Overall, these results demonstrate that larger dams have much greater impact on the ecosystem components we measured, and hence their removal has the greatest potential for restoring river ecosystems.
Leptothrix ochracea genomes reveal potential for mixotrophic growth on Fe(II) and organic carbon
(Applied and Environmental Microbiology, 2024-08-12) Tothero, Gracee K.; Hoover, Rene L.; Farag, Ibrahim F.; Kaplan, Daniel I.; Weisenhorn, Pamela; Emerson, David; Chan, Clara S.
Leptothrix ochracea creates distinctive iron-mineralized mats that carpet streams and wetlands. Easily recognized by its iron-mineralized sheaths, L. ochracea was one of the first microorganisms described in the 1800s. Yet it has never been isolated and does not have a complete genome sequence available, so key questions about its physiology remain unresolved. It is debated whether iron oxidation can be used for energy or growth and if L. ochracea is an autotroph, heterotroph, or mixotroph. To address these issues, we sampled L. ochracea-rich mats from three of its typical environments (a stream, wetlands, and a drainage channel) and reconstructed nine high-quality genomes of L. ochracea from metagenomes. These genomes contain iron oxidase genes cyc2 and mtoA, showing that L. ochracea has the potential to conserve energy from iron oxidation. Sox genes confer potential to oxidize sulfur for energy. There are genes for both carbon fixation (RuBisCO) and utilization of sugars and organic acids (acetate, lactate, and formate). In silico stoichiometric metabolic models further demonstrated the potential for growth using sugars and organic acids. Metatranscriptomes showed a high expression of genes for iron oxidation; aerobic respiration; and utilization of lactate, acetate, and sugars, as well as RuBisCO, supporting mixotrophic growth in the environment. In summary, our results suggest that L. ochracea has substantial metabolic flexibility. It is adapted to iron-rich, organic carbon-containing wetland niches, where it can thrive as a mixotrophic iron oxidizer by utilizing both iron oxidation and organics for energy generation and both inorganic and organic carbon for cell and sheath production. IMPORTANCE Winogradsky's observations of L. ochracea led him to propose autotrophic iron oxidation as a new microbial metabolism, following his work on autotrophic sulfur-oxidizers. While much culture-based research has ensued, isolation proved elusive, so most work on L. ochracea has been based in the environment and in microcosms. Meanwhile, the autotrophic Gallionella became the model for freshwater microbial iron oxidation, while heterotrophic and mixotrophic iron oxidation is not well-studied. Ecological studies have shown that Leptothrix overtakes Gallionella when dissolved organic carbon content increases, demonstrating distinct niches. This study presents the first near-complete genomes of L. ochracea, which share some features with autotrophic iron oxidizers, while also incorporating heterotrophic metabolisms. These genome, metabolic modeling, and transcriptome results give us a detailed metabolic picture of how the organism may combine lithoautotrophy with organoheterotrophy to promote Fe oxidation and C cycling and drive many biogeochemical processes resulting from microbial growth and iron oxyhydroxide formation in wetlands.
Insight into the Evolution of the Eastern Margin of the Wyoming Craton from Complex, Laterally Variable Shear Wave Splitting
(Lithosphere, 2024-07-12) Birkey, Andrew; Ford, Heather A.; Anderson, Megan; Byrnes, Joseph S.; Bezada, Maximiliano J.; Shapovalov, Maxim
Dense seismic arrays such as EarthScope’s Transportable Array (TA) have enabled high-resolution seismic observations that show the structure of cratonic lithosphere is more heterogeneous and complex than previously assumed. In this study, we pair TA data with data from the Bighorn Arch Seismic Experiment and the Crust and lithosphere Investigation of the Easternmost expression of the Laramide Orogeny (CIELO) to provide unprecedented detail on the seismic anisotropic structure of the eastern margin of the Wyoming Craton, where several orogens emerged from nominally strong cratonic lithosphere during the Laramide Orogeny. In this study, we use the splitting of teleseismic shear waves to characterize fabrics associated with deformation in the Earth’s crust and mantle. We constrain distinct anisotropic domains in the study area, and forward modeling shows that each of these domains can be explained by a single layer of anisotropy. Most significantly, we find a fast direction in the southern part of the Powder River Basin, which we refer to as the Thunder Basin Block (TBB), that deviates from absolute plate motion (APM). This change in splitting behavior coincides with changes in other modeled geophysical observations, such as active source P-wave velocity models, potential field modeling, and seismic attenuation analysis, which all show a significant change moving from the Bighorn Mountains to the TBB. We argue that these results correspond to structure predating the Laramide Orogeny, and most likely indicate a Neoarchean boundary preserved within the lithosphere.
Development of an efficient, effective, and economical technology for proteome analysis
(Cell Reports: Methods, 2024-06-11) Martin, Katherine R.; Le, Ha T.; Abdelgawad, Ahmed; Yang, Canyuan; Lu, Guotao; Keffer, Jessica L.; Zhang, Xiaohui; Zhuang, Zhihao; Asare-Okai, Papa Nii; Chan, Clara S.; Batish, Mona; Yu, Yanbao
Highlights • Rapid, robust, and cost-effective alternative to proteomics sample preparation • Versatile filter devices can meet a wide range of proteomics analysis needs • On-filter in-cell digestion facilitates low-input proteomics • Ready-to-go E3 and E4 filter devices are available Motivation Conventional proteomics sample processing methods often have high technical barriers to broad biomedical scientists, leading to difficulties for quick adoption and standardization. Existing protocols are also typically associated with costly reagents and accessories, making them less feasible for resource-limited settings as well as for clinical proteomics and/or core facilities where large numbers of samples are usually processed. Thus, there is a strong unmet need for an easy-to-use, reliable, and low-cost approach for general proteomics sample preparation. Summary We present an efficient, effective, and economical approach, named E3technology, for proteomics sample preparation. By immobilizing silica microparticles into the polytetrafluoroethylene matrix, we develop a robust membrane medium, which could serve as a reliable platform to generate proteomics-friendly samples in a rapid and low-cost fashion. We benchmark its performance using different formats and demonstrate them with a variety of sample types of varied complexity, quantity, and volume. Our data suggest that E3technology provides proteome-wide identification and quantitation performance equivalent or superior to many existing methods. We further propose an enhanced single-vessel approach, named E4technology, which performs on-filter in-cell digestion with minimal sample loss and high sensitivity, enabling low-input and low-cell proteomics. Lastly, we utilized the above technologies to investigate RNA-binding proteins and profile the intact bacterial cell proteome. Graphical abstract available at: https://doi.org/10.1016/j.crmeth.2024.100796
Incorporating flowpaths as an explicit measure of river-floodplain connectivity to improve estimates of floodplain sediment deposition
(Geomorphica, 2024-05-28) Sumaiya, Sumaiya; Schubert, John T.; Czuba, Jonathan A.; Pizzuto, James E.
Variation in floodplain topography can lead to gradual flooding and increase river-floodplain connectivity. We show that incorporating flowpaths as an explicit measure of river-floodplain connectivity can improve estimates of floodplain sediment deposition. We focus on the floodplain of the South River, downstream of Waynesboro, Virginia, where measurements of mercury accumulation have been used to estimate decadal-scale sedimentation rates. We developed a two-dimensional Hydrologic Engineering Center's River Analysis System (2D HEC-RAS) hydrodynamic model and used simulated model results with sediment deposition data to create regression models describing sedimentation across the floodplain. All of our statistical models incorporated a flowpath length from the location on the floodplain downstream to the riverbank as an explicit measure of river-floodplain connectivity that improved our estimates of floodplain sediment deposition (r2 = 0.514). We applied our best regression model to our hydrodynamic model results to create a map of floodplain sedimentation rate and discuss differences of three separate sections of floodplain. We found that floodplains with variable topography had wider, bimodal probability distribution functions (PDFs) of sedimentation rate (aggregated spatially) than floodplains without this topographic relief (with narrower log-normal PDFs). Our work highlights how floodplain topography and river-floodplain connectivity affect sedimentation rates and can help inform the development of floodplain sediment budgets.
Magmatic conditions aiding synconvergent extension above the Peruvian flat slab
(Geosphere, 2024-05-17) Grambling, Tyler A.; Jessup, Micah J.; Newell, Dennis L.; Grambling, Nadine L.; Hiett, Coleman D.
The Cordillera Blanca and Cordillera Huayhuash contain some of the highest topography in the Andes and provide insight into tectonomagmatic processes associated with the onset of flat-slab subduction. These adjacent ranges shared a similar history of deformation and exhumation prior to the late Miocene, when synconvergent extension began in the Cordillera Blanca. Magmatism in the Cordillera Huayhuash has been inferred as coeval with magmatism in the Cordillera Blanca. Yet, extension, which has been correlated with magmatic heat flow, is limited to the Cordillera Blanca. New zircon U-Pb dates and trace and rare earth element concentrations from the Cordillera Blanca batholith and the Huayllapa pluton in the Cordillera Huayhuash and reassessment of existing zircon data help to characterize regional magmatic processes prior to the establishment of flat-slab subduction. Two compositionally distinct samples of the Huayllapa pluton yielded mean ages of 24.8 ± 0.4 Ma and 25.4 ± 0.8 Ma. In contrast, the Cordillera Blanca batholith has a protracted crystallization history postdating that of the Cordillera Huayhuash by up to 20 m.y. Miocene magmatism in the Cordillera Blanca began at 19 Ma and ended with injection of large volumes of geochemically distinct, mantle-derived magma from 10 to 5 Ma. We suggest that 6–5 Ma magmatism in the Cordillera Blanca promoted elevated heat flow and reduced shear strength, which facilitated extensional shearing along the western slopes of the range, whereas colder amagmatic crust in the Cordillera Huayhuash inhibited southward propagation of faulting. Our data demonstrate that the linkages between magmatism and elevated heat flow identified in the Cordillera Blanca are important driving processes in initiating extension in cordilleran-style orogenies.
Saltwater Intrusion Into a Confined Island Aquifer Driven by Erosion, Changing Recharge, Sea-Level Rise, and Coastal Flooding
(Water Resources Research, 2024-01-08) Stanic, S.; LeRoux, N. K.; Paldor, A.; Mohammed, A. A.; Michael, H. A.; Kurylyk, B. L.
Aquifers on small islands are at risk of salinization due to low elevations and limited adaptive capacity, and present risks will be exacerbated by climate change. Most studies addressing small-island saltwater intrusion (SWI) have focused on homogeneous sandy islands and one or two hydraulic disturbances. We herein investigate SWI dynamics in a layered, confined island aquifer in response to multiple environmental perturbations related to climate change, with two considered in tandem. Our field and modeling work is based on an island aquifer that provides the drinking water supply for an Indigenous community in Atlantic Canada. Observation well data and electrical resistivity profiles were used to calibrate a numerical model (HydroGeoSphere) of coupled groundwater flow and salt transport. The calibrated model was used to simulate the impacts of climate change including sea-level rise (SLR), storm surge overtopping, changing aquifer recharge, and erosion. Simulated aquifer conditions were resilient to surges because the confining layer prevented deeper saltwater leaching. However, reduced recharge and erosion resulted in saltwater wedge migration of 170 and 110 m, respectively when considered individually, and up to 295 m (i.e., into the wellfield) when considered together. Despite the confining conditions, SLR resulted in wedge migration up to 55 m as the confining pressures were not sufficient to resist wedge movement. This is the first study to harness an integrated, surface-subsurface hydrologic model to assess effects of coastal erosion and other hydroclimatic stressors on island aquifers, highlighting that climate change can drive extensive salinization of critical groundwater resources. Key Points - A surface-subsurface numerical model is used to investigate climate change impacts on island groundwater resources used for water supply - The confined aquifer is resilient to storm surges which only salinize the unpumped surficial aquifer before being flushed - Coastal erosion and recharge reductions result in the most saltwater intrusion and can work in tandem to threaten future water supply Plain Language Summary Due to their limited resources and adaptive capacity, small islands are highly vulnerable to climate change impacts, including saltwater intrusion. Freshwater needs on small islands are often sourced from small aquifers that are in delicate balance between conditions in the ocean, atmosphere, and land. In this study, we investigate the movement of saltwater into the freshwater aquifer of a small island that provides drinking water resources for an Indigenous First Nation. We consider climatic changes in the ocean (sea-level rise (SLR), storm surges, and related coastal erosion) and atmosphere (changes to net precipitation) and associated impacts to the island's fresh groundwater resources. We use field data paired with a mathematical model and demonstrate that the pressurized conditions of the layered island aquifer make it more resilient to SLR than unconfined aquifers in sandy islands are. However, the aquifer's freshwater volume is susceptible to coastal erosion and reduced precipitation, particularly when these happen at the same time. Results point to coastal erosion as a potential widespread driver of freshwater loss along eroding portions of the global coastline.
Trace elements in abyssal peridotite olivine record melting, thermal evolution, and melt refertilization in the oceanic upper mantle
(Contributions to Mineralogy and Petrology, 2023-09-06) Lin, Kuan-Yu; Warren, Jessica M.; Davis, Fred A.
Trace element concentrations in abyssal peridotite olivine provide insights into the formation and evolution of the oceanic lithosphere. We present olivine trace element compositions (Al, Ca, Ti, V, Cr, Mn, Co, Ni, Zn, Y, Yb) from abyssal peridotites to investigate partial melting, melt–rock interaction, and subsolidus cooling at mid-ocean ridges and intra-oceanic forearcs. We targeted 44 peridotites from fast (Hess Deep, East Pacific Rise) and ultraslow (Gakkel and Southwest Indian Ridges) spreading ridges and the Tonga trench, including 5 peridotites that contain melt veins. We found that the abundances of Ti, Mn, Co, and Zn increase, while Ni decreases in melt-veined samples relative to unveined samples, suggesting that these elements are useful tracers of melt infiltration. The abundances of Al, Ca, Cr, and V in olivine are temperature sensitive. Thermometers utilizing Al and Ca in olivine indicate temperatures of 650–1000 °C, with variations corresponding to the contrasting cooling rates the peridotites experienced in different tectonic environments. Finally, we demonstrate with a two-stage model that olivine Y and Yb abundances reflect both partial melting and subsolidus re-equilibration. Samples that record lower Al- and Ca-in-olivine temperatures experienced higher extents of diffusive Y and Yb loss during cooling. Altogether, we demonstrate that olivine trace elements document both high-temperature melting and melt–rock interaction events, as well as subsolidus cooling related to their exhumation and emplacement onto the seafloor. This makes them useful tools to study processes associated with seafloor spreading and mid-ocean ridge tectonics.
Pre- and postsettlement depositional processes and environments of the 3rd- to 5th-order White Clay Creek watershed, Piedmont Province, Pennsylvania and Delaware, USA
(GSA Bulletin, 2023-08-23) Pizzuto, J.E.; Huffman, M. E.; Symes, E.
We extend two hypotheses based on studies of 1st- to 3rd-order Piedmont watersheds of southeastern Pennsylvania, USA, by collecting data in a larger 3rd- to 5th-order watershed nearby. One hypothesis posits that presettlement river corridors were dominated by wetlands, and the other suggests that river valleys were filled by millpond sedimentation following European settlement. Both hypotheses support new river restoration practices, so their generality is important to assess. Ten lithofacies indicate depositional environments, while pedostratigraphic criteria and 14C dating define presettlement and postsettlement stratigraphic units. Basal gravels similar to modern stream bed sediments represent presettlement channels with active bedload transport. Wedge-shaped gravel deposits resembling modern bars further document presettlement bedload transport by channelized flows. Extensive presettlement and postsettlement units of massive, organic-poor, fine-grained sediment formed when overbank flows inundated floodplains. Peat deposits, exposed at a single site (but absent elsewhere), represent a presettlement wetland. Decimeter-thick, discontinuous, massive carbonaceous fine-grained sediments occasionally overlie basal gravels; these may represent localized wetlands adjacent to presettlement channels or hydraulic backwater environments. Laminated sand and mud accumulated behind one 3-m-high mill dam, but these millpond deposits are absent at other sites. Instead of being dominated by wetlands, presettlement river corridors are better described as a complex mosaic of riparian environments including older colluvial landforms, floodplains (some of which may have been seasonally inundated wetlands), primary (and possibly secondary) channels, and depending on geomorphic setting, either localized or valley-spanning wetlands. After European settlement, millponds were important locally, but their deposits represent a minor component of the stratigraphic record.
Physiochemical Controls on the Horizontal Exchange of Blue Carbon Across the Salt Marsh-Tidal Channel Interface
(Journal of Geophysical Research: Biogeosciences, 2023-06-06) Fettrow, Sean; Jeppi, Virginia; Wozniak, Andrew; Vargas, Rodrigo; Michael, Holly; Seyfferth, Angelia L.
Tidal channels are biogeochemical hotspots that horizontally exchange carbon (C) with marsh platforms, but the physiochemical drivers controlling these dynamics are poorly understood. We hypothesized that C-bearing iron (Fe) oxides precipitate and immobilize dissolved organic carbon (DOC) during ebb tide as the soils oxygenate, and dissolve into the porewater during flood tide, promoting transport to the channel. The hydraulic gradient physically controls how these solutes are horizontally exchanged across the marsh platform-tidal channel interface; we hypothesized that this gradient alters the concentration and source of C being exchanged. We further hypothesized that trace soil gases (i.e., CO2, CH4, dimethyl sulfide) are pushed out of the channel bank as the groundwater rises. To test these hypotheses, we measured porewater, surface water, and soil trace gases over two 24-hr monitoring campaigns (i.e., summer and spring) in a mesohaline tidal marsh. We found that Fe2+ and DOC were positively related during flood tide but not during ebb tide in spring when soils were more oxidized. This finding shows evidence for the formation and dissolution of C-bearing Fe oxides across a tidal cycle. In addition, the tidal channel contained significantly (p < 0.05) more terrestrial-like DOC when the hydraulic gradient was driving flow toward the channel. In comparison, the channel water was saltier and contained significantly (p < 0.05) more marine-like DOC when the hydraulic gradient reversed direction. Trace gas fluxes increased with rising groundwater levels, particularly dimethyl sulfide. These findings suggest multiple physiochemical mechanisms controlling the horizontal exchange of C at the marsh platform-tidal channel interface. Plain Language Summary Tidal salt marshes store large amounts of carbon belowground in soils, but there is also a significant amount of carbon flowing into and out of these ecosystems via tidal channels. We investigated the carbon flowing between the channel bank and surface water in a salt marsh in Delaware. We found that soil minerals (i.e., iron oxides) control the mobility of carbon as iron oxides retain carbon during ebb tides and release carbon during flood tides as the minerals dissolve. The gradient between the groundwater and surface water elevation (i.e., hydraulic gradient) controls the flow direction for dissolved carbon, altering the concentration and source of carbon found in the tidal channel across tidal cycles. In addition, gases trapped in channel banks are pushed out of the soils as the tide rises. These findings will improve our understanding of carbon cycles in these critical carbon sinks. Key Points - Physiochemical mechanisms control horizontal exchange of carbon across marsh-tidal channel interfaces, affecting lateral carbon flux - Dissolution and reprecipitation of carbon-bearing Fe oxides during flood and ebb tides control the horizontal mobility of carbon - Hydraulic gradients control the carbon character in the tidal channel, and rising tides push greenhouse gases out of the channel bank

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