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Open access publications by faculty, postdocs, and graduate students in the Department of Earth Sciences.

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Along-Shore Movement of Groundwater and Its Effects on Seawater-Groundwater Interactions in Heterogeneous Coastal Aquifers
(Water Resources Research, 2021-12-14) Geng, Xiaolong; Michael, Holly A.
Studies of coastal groundwater dynamics often assume two-dimensional (2D) flow and transport along a shore-perpendicular cross-section. We show that along-shore movement of groundwater may also be significant in heterogeneous coastal aquifers. Simulations of groundwater flow and salt transport incorporating different geologic structure show highly three-dimensional (3D) preferential flow paths. The along-shore movement of groundwater on average accounts for 40%–50% of the total flowpath length in both conduit-type (e.g., volcanic) heterogeneous aquifers and statistically equivalent (e.g., deltaic) systems generated with sequential indicator simulation (SIS). Our results identify a critical role of three-dimensionality in systems with connected high-permeability geological features. 3D conduit features connecting land and sea cause more terrestrial groundwater flow through the inland boundary and intensify water exchange along the land-sea interface. Therefore, conduits increase the rate of SGD compared to equivalent homogeneous, SIS and corresponding 2D models. In contrast, in SIS-type systems, less-connected high-permeability features produce mixing zones and SGD nearer to shore, with comparable rates in 3D and 2D models. Onshore, 3D heterogeneous cases have longer flowpaths and travel times from recharge to discharge compared to 2D cases, but offshore travel times are much shorter, particularly for conduit-type models in which flow is highly preferential. Flowpath lengths and travel times are also highly variable in 3D relative to 2D for all heterogeneous simulations. The results have implications for water resources management, biogeochemical reactions within coastal aquifers, and subsequent chemical fluxes to the ocean. Plain Language Summary: The findings of this study provide insight into the complex patterns of groundwater flow under the influence of geologic variability in coastal aquifers. In coastal regions, studies of solute transport processes mainly rely on an assumption of 2D groundwater flow and solute transport in the shore-perpendicular direction. Our results reveal that groundwater does not only flow toward the sea, it also can flow along-shore, especially in aquifers with features that connect the onshore and offshore. This affects exchange and mixing between fresh and saline groundwater, which can strongly impact delivery of contaminants and nutrients to sensitive nearshore marine ecosystems. Results highlight the importance of characterizing the geology of coastal aquifers and representing it in models of groundwater flow and contaminant transport.
Coastal topography and hydrogeology control critical groundwater gradients and potential beach surface instability during storm surges
(Hydrology and Earth System Sciences, 2022-12-02) Paldor, Anner; Stark, Nina; Florence, Matthew; Raubenheimer, Britt; Elgar, Steve; Housego, Rachel; Frederiks, Ryan S.; Michael, Holly A.
Ocean surges pose a global threat for coastal stability. These hazardous events alter flow conditions and pore pressures in flooded beach areas during both inundation and subsequent retreat stages, which can mobilize beach material, potentially enhancing erosion significantly. In this study, the evolution of surge-induced pore-pressure gradients is studied through numerical hydrologic simulations of storm surges. The spatiotemporal variability of critically high gradients is analyzed in three dimensions. The analysis is based on a threshold value obtained for quicksand formation of beach materials under groundwater seepage. Simulations of surge events show that, during the run-up stage, head gradients can rise to the calculated critical level landward of the advancing inundation line. During the receding stage, critical gradients were simulated seaward of the retreating inundation line. These gradients reach maximum magnitudes just as sea level returns to pre-surge levels and are most accentuated beneath the still-water shoreline, where the model surface changes slope. The gradients vary along the shore owing to variable beach morphology, with the largest gradients seaward of intermediate-scale (1–3 m elevation) topographic elements (dunes) in the flood zone. These findings suggest that the common practices in monitoring and mitigating surge-induced failures and erosion, which typically focus on the flattest areas of beaches, might need to be revised to include other topographic features.
Critical facility accessibility and road criticality assessment considering flood-induced partial failure
(Sustainable and Resilient Infrastructure, 2022-11-25) Gangwal, Utkarsh; Siders, A. R.; Horney, Jennifer; Michael, Holly A.; Dong, Shangjia
This paper examines communities’ accessibility to critical facilities such as hospitals, emergency medical services, and emergency shelters when facing flooding. We use travel speed reduction to account for flood-induced partial road failure. A modified betweenness centrality metric is also introduced to calculate the criticality of roads for connecting communities to critical facilities. The proposed model and metric are applied to the Delaware road network under 100-year floods. This model highlights the severe critical facility access loss risk due to flood isolation of facilities. The mapped post-flooding accessibility suggests a significant travel time increase to critical facilities and reveals disparities among communities, especially for vulnerable groups such as long-term care facility residents. We also identified critical roads that are vital for post-flooding access to critical facilities. The results of this research can help inform targeted infrastructure investment decisions and hazard mitigation strategies that contribute to equitable community resilience enhancement.
Dynamic Steady State in Coastal Aquifers Is Driven by Multi-Scale Cyclical Processes, Controlled by Aquifer Storativity
(Geophysical Research Letters, 2022-05-24) Paldor, Anner; Frederiks, Ryan S.; Michael, Holly A.
Coastal aquifers supply freshwater to nearly half the global population, yet they are threatened by salinization. Salinities are typically estimated assuming steady-state, neglecting the effect of cyclical forcings on average salinity distributions. Here, numerical modeling is used to test this assumption. Multi-scale fluctuations in sea level (SL) are simulated, from tides to glacial cycles. Results show that high-frequency fluctuations alter average salinities compared with the steady-state distribution produced by average SL. Low-frequency forcing generates discrepancies between present-day salinities estimated with and without considering the cyclical forcing due to overshoot effects. This implies that salinities in coastal aquifers may be erroneously estimated when assuming steady-state conditions, since present distributions are likely part of a dynamic steady state that includes forcing on multiple timescales. Further, typically neglected aquifer storage characteristics can strongly control average salinity distributions. This has important implications for managing vulnerable coastal groundwater resources and for calibration of hydrogeological models. Key Points: - Average salinities in coastal aquifers are affected by low-frequency cyclical changes in sea level (SL) - High-frequency cyclical forcings generate episodic discrepancies in salinity when modeled with and without considering these processes - Under these multi-scale fluctuations in SL, dynamic steady states of coastal aquifers are affected by aquifer storage properties Plain Language Summary: Coastal communities rely heavily on groundwater for freshwater supply, and the primary risk for this vital resource is salinization. Multiple processes in the ocean-land interface control the salinity of coastal aquifers, and assessments of salinities typically neglect some of these processes. In this work, we show that some of the typically neglected processes may be responsible for large-scale, systematic discrepancies between actual and estimated salinities. This has important implications for the assessment of risks to coastal groundwater reservoirs and for the long-term management of these resources.
Effects of Geologic Setting on Contaminant Transport in Deltaic Aquifers
(Water Resources Research, 2022-08-25) Xu, Zhongyuan; Hariharan, Jayaram; Passalacqua, Paola; Steel, Elisabeth; Chadwick, Austin; Paola, Chris; Paldor, Anner; Michael, Holly A.
Coastal deltaic aquifers are vulnerable to degradation from seawater intrusion, geogenic and anthropogenic contamination, and groundwater abstraction. The distribution and transport of contaminants are highly dependent on the subsurface sedimentary architecture, such as the presence of channelized features that preferentially conduct flow. Surface deposition changes in response to sea-level rise (SLR) and sediment supply, but it remains unclear how these surface changes affect the distribution and transport of groundwater solutes in aquifers. Here, we explore the influence of SLR and sediment supply on aquifer heterogeneity and resulting effects on contaminant transport. We use realizations of subsurface heterogeneity generated by a process-based numerical model, DeltaRCM, which simulates the evolution of a deltaic aquifer with different input sand fractions and rates of SLR. We simulate groundwater flow and solute transport through these deposits in three contamination scenarios: (a) vertical transport from widespread contamination at the land surface, (b) vertical transport from river water infiltration, and (c) lateral seawater intrusion. The simulations show that the vulnerability of deltaic aquifers to seawater intrusion correlates to sand fraction, while vertical transport of contaminants, such as widespread shallow contamination and river water infiltration, is influenced by channel stacking patterns. This analysis provides new insights into the connection between the depositional system properties and vulnerability to different modes of groundwater contamination. It also illustrates how vulnerability may vary locally within a delta due to depositional differences. Results suggest that groundwater management strategies may be improved by considering surface features, location within the delta, and the external forcings during aquifer deposition. Plain Language Summary: The findings of this study provide insight into the vulnerability of deltaic aquifers to three contamination processes: (a) widespread contaminant transport from the land surface, (b) river water infiltration, and (c) seawater intrusion. We consider how contamination is affected by the location of contaminants and the processes associated with the accumulation of sediments in deltas. Our work shows that vulnerability to contamination depends on how the aquifer is deposited. The results also demonstrate that the distribution of sandy channels preserved in the subsurface, as well as rivers on the surface, controls vertical contaminant transport. We find that these effects vary from upstream to downstream in the delta because of spatial differences in depositional processes. These findings will help to improve predictions of groundwater contamination and manage groundwater development in deltas around the world.
Floodplain Sediment Storage Timescales of the Laterally Confined Meandering Powder River, USA
(Journal of Geophysical Research: Earth Surface, 2022-01-11) Huffman, Max E.; Pizzuto, James E.; Trampush, Sheila M.; Moody, John A.; Schook, Derek M.; Gray, Harrison J.; Mahan, Shannon A.
As sediment is transported through river corridors, it typically spends more time in storage than transport, and as a result, sediment delivery timescales are controlled by the duration of storage. Present understanding of storage timescales is largely derived from models or from field studies covering relatively short (≤102 year) time spans. Here we quantify the storage time distribution for a 17 km length of Powder River in Montana, USA by determining the age distribution of eroded sediment. Our approach integrates surveyed cross-sections, analysis of historical aerial imagery, aerial LiDAR, geomorphic mapping, and age control provided by optically stimulated luminescence (OSL) and dendrochronology. Sediment eroded by Powder River from 1998 to 2013 ranges from a few years to ∼5,000 years in age; ages are exponentially distributed (r2 = 0.78; Anderson-Darling p value 0.003). Eroded sediment is derived from Powder River's meander belt (∼900 m wide), which is only 1.25 times its meander wavelength, a value reflecting valley confinement rather than free meandering. The mean storage time, 824 years (95% C.I. 610–1030 years), is similar to the time required to rework deposits of Powder River's meander belt based on an average meander migration rate of ∼1 m/yr, implying that storage time distributions of confined meandering rivers can be quantified from remotely sensed estimates of meander belt width and channel migration rates. Heavy-tailed storage time distributions, frequently cited from physical and numerical modeling studies, may be restricted to unconfined meandering rivers. Plain Language Summary: As sediment moves downstream through a watershed it is intermittently stored in a river's deposits before being eroded and transported farther downstream. Storage times vary from less than a decade to millennia. Storage time greatly exceeds the time sediment is being transported by the river. Consequently, the time required for sediment to reach a point downstream is largely controlled by the time spent in storage. This can influence how the movement of contaminants are monitored and restoration strategies are developed. Sediment particles spend different amounts of time in storage, which can be represented as a probability distribution. Here we date sediment eroded by Powder River in southeastern Montana from 1998 to 2013 and find that the storage time distribution is exponential. Furthermore, the mean storage time of 824 years (which fully characterizes the exponential distribution) can be determined from the meander belt width and the channel migration rate, both of which can be measured using aerial imagery, providing a simple method for assessing storage times in laterally confined rivers.
Hydrogen Diffusion in Clinopyroxene at Low Temperatures (195°C–400°C) and Consequences for Subsurface Processes
(Geochemistry, Geophysics, Geosystems, 2022-12-12) Bissbort, Thilo; Lynn, Kendra J.; Becker, Hans-Werner; Chakraborty, Sumit
Studying diffusion of hydrogen in nominally anhydrous minerals, like clinopyroxene, at low temperatures is a challenging task due to experimental and analytical difficulties. In this study, to overcome these problems we have produced H concentration gradients in single crystals of natural diopsidic clinopyroxene by ion implantation and measured the nanoscale profiles before and after diffusion anneals using Nuclear Resonance Reaction Analysis. These steps allowed us to conduct experiments at temperatures between 195°C and 400°C. Obtained diffusion rates show a consistent Arrhenius relation DH= 5.47(±13.98) · 10−8 · exp (−115.64(±11.5) kJ mol−1/RT) m2s−1. Notably, our results lie well within the range of extrapolations from high temperature experiments (≥600°C) of previous studies. This implies that fast diffusion of hydrogen (compared to other elements) extends to low temperatures. We used these results in a non-isothermal diffusion model that simulates the ascent of crystals (0.5, 1.0, and 2.0 mm) along two representative P-T-paths from 600°C to 100°C, to assess potential re-equilibration of H contents in clinopyroxene at low temperatures. Our model highlights the need to carefully consider boundary conditions, which are a function of P-T-fO2, that control the concentration gradient at the crystal's rim. The results from this model help to assess, as a function of crystal size and cooling rate, when re-equilibration must be considered. Key Points - Diffusion rates of hydrogen in clinopyroxene in the low temperature range (195°C–400°C) were quantified for the first time - Diffusion coefficients at low temperatures lie within the range of extrapolations from high temperature experiments - Non-isothermal modeling was applied to evaluate potential re-equilibration of clinopyroxene crystals at low temperatures
Hydrologic Control on Arsenic Cycling at the Groundwater–Surface Water Interface of a Tidal Channel
(Environmental Science and Technology, 2023-01-10) Yu, Xuan; LeMonte, Joshua J.; Li, Junxia; Stuckey, Jason W.; Sparks, Donald L.; Cargill, John G.; Russoniello, Christopher J.; Michael, Holly A.
Historical industrial activities have resulted in soil contamination at sites globally. Many of these sites are located along coastlines, making them vulnerable to hydrologic and biogeochemical alterations due to climate change and sea-level rise. However, the impact of hydrologic dynamics on contaminant mobility in tidal environments has not been well studied. Here, we collected data from pressure transducers in wells, multi-level redox sensors, and porewater samplers at an As-contaminated site adjacent to a freshwater tidal channel. Results indicate that sharp redox gradients exist and that redox conditions vary on tidal to seasonal timescales due to sub-daily water level fluctuations in the channel and seasonal groundwater–surface water interactions. The As and Fe2+ concentrations decreased during seasonal periods of net discharge to the channel. The seasonal changes were greater than tidal variations in both Eh and As concentrations, indicating that impacts of the seasonal mechanism are stronger than those of sub-daily water table fluctuations. A conceptual model describing tidal and seasonal hydro-biogeochemical coupling is presented. These findings have broad implications for understanding the impacts of sea-level rise on the mobility of natural and anthropogenic coastal solutes.
Iron Oxidation by a Fused Cytochrome-Porin Common to Diverse Iron-Oxidizing Bacteria
(mBio, 2021-07-27) Keffer, Jessica L.; McAllister, Sean M.; Garber, Arkadiy I.; Hallahan, Beverly J.; Sutherland, Molly C.; Rozovsky, Sharon; Chan, Clara S.
Iron (Fe) oxidation is one of Earth’s major biogeochemical processes, key to weathering, soil formation, water quality, and corrosion. However, our understanding of microbial contribution is limited by incomplete knowledge of microbial iron oxidation mechanisms, particularly in neutrophilic iron oxidizers. The genomes of many diverse iron oxidizers encode a homolog to an outer membrane cytochrome (Cyc2) shown to oxidize iron in two acidophiles. Phylogenetic analyses show Cyc2 sequences from neutrophiles cluster together, suggesting a common function, though this function has not been verified in these organisms. Therefore, we investigated the iron oxidase function of heterologously expressed Cyc2 from a neutrophilic iron oxidizer Mariprofundus ferrooxydans PV-1. Cyc2PV-1 is capable of oxidizing iron, and its redox potential is 208 ± 20 mV, consistent with the ability to accept electrons from Fe2+ at neutral pH. These results support the hypothesis that Cyc2 functions as an iron oxidase in neutrophilic iron-oxidizing organisms. The results of sequence analysis and modeling reveal that the entire Cyc2 family shares a unique fused cytochrome-porin structure, with a defining consensus motif in the cytochrome region. On the basis of results from structural analyses, we predict that the monoheme cytochrome Cyc2 specifically oxidizes dissolved Fe2+, in contrast to multiheme iron oxidases, which may oxidize solid Fe(II). With our results, there is now functional validation for diverse representatives of Cyc2 sequences. We present a comprehensive Cyc2 phylogenetic tree and offer a roadmap for identifying cyc2/Cyc2 homologs and interpreting their function. The occurrence of cyc2 in many genomes beyond known iron oxidizers presents the possibility that microbial iron oxidation may be a widespread metabolism.
Linking the Surface and Subsurface in River Deltas—Part 2: Relating Subsurface Geometry to Groundwater Flow Behavior
(Water Resources Research, 2021-08-02) Xu, Zhongyuan; Hariharan, Jayaram; Passalacqua, Paola; Steel, Elisabeth; Paola, Chris; Michael, Holly A.
Understanding subsurface structure and groundwater flow in deltaic aquifers is essential for evaluating the vulnerability of groundwater resources in delta systems. Deltaic aquifers contain coarse-grained paleochannels that preserve a record of former surface river channels as well as fine-grained floodplain deposits. The distribution of these deposits and how they are interconnected control groundwater flow and contaminant transport. In this work, we link depositional environments of deltaic aquifers to stratigraphic (static) and flow and transport (dynamic) connectivity metrics. Numerical models of deltaic stratigraphy were generated using a reduced-complexity numerical model (DeltaRCM) with different input sand fractions (ISF) and rates of sea-level rise (SLR). The groundwater flow and advective transport behavior of these deltas were simulated using MODFLOW and MODPATH. By comparing the static and dynamic metrics calculated from these numerical models, we show that groundwater behavior can be predicted by particular aspects of the subsurface architecture, and that horizontal and vertical connectivity display different characteristics. We also evaluate relationships between connectivity metrics and two environmental controls on delta evolution: ISF and SLR rate. The results show that geologic setting strongly influences both static and dynamic connectivity in different directions. These results provide insights into quantitatively differentiated subsurface hydraulic behavior between deltas formed under different external forcing (ISF and SLR rate) and they are a potential link in using information from delta surface networks and depositional history to predict vulnerability to aquifer contamination. Plain Language Summary: Geologic structure and groundwater flow behaviors influence groundwater resources in delta plains. In deltaic aquifers, channel structures were created by past surface rivers. These channels in the subsurface are “fast-travel” pathways for groundwater and contaminants. We created synthetic delta structures with a numerical model and then simulated groundwater flow through them in order to tie geologic structure to groundwater flow behavior. By using many different models, we investigate how structure and flow relate, and how the subsurface geology and groundwater system are affected by different sediment inputs and sea-level rise rates. The findings will help us better manage delta groundwater resources and provide an opportunity to predict groundwater contamination from surface characteristics.
Spatially averaged stratigraphic data to inform watershed sediment routing: An example from the Mid-Atlantic United States
(Geological Society of America Bulletin, 2022-05-05) Pizzuto, James E.; Skalak, K.J.; Benthem, A.; Mahan, S.A.; Sherif, M.; Pearson, A.J.
New and previously published stratigraphic data define Holocene to present sediment storage time scales for Mid-Atlantic river corridors. Empirical distributions of deposit ages and thicknesses were randomly sampled to create synthetic age-depth records. Deposits predating European settlement accumulated at a (median) rate of 0.06 cm yr−1, range from ∼18,000 to 225 yr old, and represent 39% (median) of the total accumulation. Sediments deposited from 1750 to 1950 (“legacy sediments”) accumulated at a (median) rate of 0.39 cm yr−1 and comprise 47% (median) of the total, while “modern sediments” (1950−present) represent 11% of the total and accumulated at a (median) rate of 0.25 cm yr−1. Synthetic stratigraphic sequences, recast as age distributions for the presettlement period, in 1900 A.D., and at present, reflect rapid postsettlement alluviation, with enhanced preservation of younger sediments related to postsettlement watershed disturbance. An averaged present age distribution for vertically accreted sediment has modal, median, and mean ages of 190, 230, and 630 yr, reflecting the predominance of stored legacy sediments and the influence of relatively few, much older early Holocene deposits. The present age distribution, if represented by an exponential approximation (mean age ∼300 yr), and naively assumed to represent steady-state conditions, implies median sediment travel times on the order of centuries for travel distances greater than ∼100 km. The percentage of sediment reaching the watershed outlet in 30 yr (a reasonable time horizon to achieve watershed restoration efficacy) is ∼60% for a distance of 50 km, but this decreases to <20% for distances greater than 200 km. Age distributions, evaluated through time, not only encapsulate the history of sediment storage, but they also provide data for calibrating watershed-scale sediment-routing models over geological time scales.
Surface Water-Groundwater Connections as Pathways for Inland Salinization of Coastal Aquifers
(Groundwater, 2022-11-17) Hingst, Mary C.; McQuiggan, Rachel W.; Peters, Chelsea N.; He, Changming; Andres, A. Scott; Michael, Holly A.
Coastal agricultural zones are experiencing salinization due to accelerating rates of sea-level rise, causing reduction in crop yields and abandonment of farmland. Understanding mechanisms and drivers of this seawater intrusion (SWI) is key to mitigating its effects and predicting future vulnerability of groundwater resources to salinization. We implemented a monitoring network of pressure and specific conductivity (SC) sensors in wells and surface waters to target marsh-adjacent agricultural areas in greater Dover, Delaware. Recorded water levels and SC over a period of three years show that the mechanisms and timescales of SWI are controlled by local hydrology, geomorphology, and geology. Monitored wells did not indicate widespread salinization of deep groundwater in the surficial aquifer. However, monitored surface water bodies and shallow (<4 m deep) wells did show SC fluctuations due to tides and storm events, in one case leading to salinization of deeper (18 m deep) groundwater. Seasonal peaks in SC occurred during late summer months. Seasonal and interannual variation of SC was also influenced by relative sea level. The data collected in this study data highlight the mechanisms by which surface water-groundwater connections lead to salinization of aquifers inland, before SWI is detected in deeper groundwater nearer the coastline. Sharing of our data with stakeholders has led to the implementation of SWI mitigation efforts, illustrating the importance of strategic monitoring and stakeholder engagement to support coastal resilience.

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