Fluoroalkyl phosphonic acid radical scavengers for proton exchange membrane fuel cells
| Author(s) | Agarwal, Tanya | |
| Author(s) | Adhikari, Santosh | |
| Author(s) | Kim, Yu Seung | |
| Author(s) | Babu, Siddharth Komini | |
| Author(s) | Tian, Ding | |
| Author(s) | Bae, Chulsung | |
| Author(s) | Pham, Nguyet N. T. | |
| Author(s) | Lee, Seung Geol | |
| Author(s) | Prasad, Ajay K. | |
| Author(s) | Advani, Suresh G. | |
| Author(s) | Sievert, Allen | |
| Author(s) | Rasika, Wipula Priya Liyanage | |
| Author(s) | Hopkins, Timothy E. | |
| Author(s) | Park, Andrew | |
| Author(s) | Borup, Rod | |
| Date Accessioned | 2024-02-28T20:10:13Z | |
| Date Available | 2024-02-28T20:10:13Z | |
| Publication Date | 2023-04-06 | |
| Description | This article was originally published in Journal of Materials Chemistry A. The version of record is available at: https://doi.org/10.1039/D2TA09421E | |
| Abstract | Radical-induced degradation of proton exchange membranes limits the durability of proton-exchange membrane fuel cells. Cerium is widely used as a radical scavenger, but the migration of cerium ions to the catalyst layer has been an unresolved issue, reducing its effectiveness over time. Here, we report phosphonic acids as a promising class of radical scavengers, showing competent radical scavenging activity compared to cerium without the migration issue. The ex situ Fenton test shows that the fluoride emission rate for Nafion membrane incorporated with fluoroalkyl phosphonic acid ranged from 0.22 to 0.37 μg F cm−2 h−1, lower than that of the cerium-incorporated Nafion™ membrane (0.39 μg F cm−2 h−1). The in situ open circuit voltage hold test confirmed that a phosphonic acid-incorporated Nafion™ membrane has a 58% lower fluoride emission rate compared to the baseline. Density functional theory calculations indicate that the activation energy of the hydroxyl radical scavenging reaction of an alkyl phosphonic acid is only 0.68 eV, suggesting an effective radical scavenging pathway. | |
| Sponsor | The US Department of Energy (US DOE), Office of Energy Efficiency and Renewable Energy (EERE), and Hydrogen and Fuel Cell Technologies office (HFTO) supported this research through the M2FCT (Million Mile Fuel Cell Truck) Consortium. | |
| Citation | Agarwal, Tanya, Santosh Adhikari, Yu Seung Kim, Siddharth Komini Babu, Ding Tian, Chulsung Bae, Nguyet N. T. Pham, et al. “Fluoroalkyl Phosphonic Acid Radical Scavengers for Proton Exchange Membrane Fuel Cells.” Journal of Materials Chemistry A 11, no. 18 (2023): 9748–54. https://doi.org/10.1039/D2TA09421E. | |
| ISSN | 2050-7496 | |
| URL | https://udspace.udel.edu/handle/19716/34073 | |
| Language | en_US | |
| Publisher | Journal of Materials Chemistry A | |
| dc.rights | Attribution-NonCommercial 4.0 International | en |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | |
| Keywords | affordable and clean energy | |
| Title | Fluoroalkyl phosphonic acid radical scavengers for proton exchange membrane fuel cells | |
| Type | Article |
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