Screen-Printable Contacts for Industrial N-TOPCon Crystalline Silicon Solar Cells

Author(s)Lu, Meijun
Author(s)Mikeska, Kurt R.
Author(s)Ni, Chaoying
Author(s)Zhao, Yong
Author(s)Chen, Feibiao
Author(s)Xie, Xianqing
Author(s)Xu, Yawen
Author(s)Zhang, Changgen
Date Accessioned2022-03-16T17:14:48Z
Date Available2022-03-16T17:14:48Z
Publication Date2022-01-13
Description© 2022 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works. This article was originally published in IEEE Journal of Photovoltaics. The version of record is available at: https://doi.org/10.1109/JPHOTOV.2021.3138248en_US
AbstractOptimally prepared industrial n -type bifacial tunnel oxide passivated contacts c-Si solar cells (156 × 156 mm) fabricated with cost effective screen-printable front-side (FS) and rear-side (RS) silver pastes had a median solar cell efficiency of 22.21% ± 0.10% and bifaciality efficiency factor of 82.9%. A FS paste comprising silver, metallic aluminum, and inorganic frit was designed to contact p+ boron-diffused Si emitter surfaces with SiN x :H–Al 2 O 3 antireflection-passivation layers. A RS paste comprising silver and inorganic frit was designed to contact n+ phosphorous-doped surfaces with tunnel-SiO x / n+ poly-Si/SiN x :H layers. The bifacial electrical data indicates efficiency is being limited by the FS contact. The final FS bulk silver metal region microstructure shows isolated metallic aluminum particles surrounded by solidified liquid phase within the bulk sintered silver conductor line. The FS silver metal- p+ boron-diffused emitter contact region shows continuous interfacial (IF) films decorated with silver colloids located between the bulk silver metal and emitter surface. The final RS silver metal- n+ phosphorus diffused contact region again shows continuous IF films between the bulk silver metal and semiconductor surface. A microstructural model suggests electrical contact for both the FS and RS contact regions occurs by a tunneling mechanism though the residual IF films.en_US
CitationM. Lu et al., "Screen-Printable Contacts for Industrial N-TOPCon Crystalline Silicon Solar Cells," in IEEE Journal of Photovoltaics, vol. 12, no. 2, pp. 469-473, March 2022, doi: 10.1109/JPHOTOV.2021.3138248.en_US
ISSN2156-3403
URLhttps://udspace.udel.edu/handle/19716/30656
Languageen_USen_US
PublisherIEEE Journal of Photovoltaicsen_US
KeywordsBifacialen_US
Keywordsfriten_US
Keywordsmetallizationen_US
Keywordsn-typeen_US
Keywordspasteen_US
Keywordsphotovoltaic cellsen_US
Keywordsscreen printen_US
Keywordssiliconen_US
Keywordssolar cellsen_US
Keywordsthick-filmen_US
Keywordstunnel oxide passivated contacts (TOPCon)en_US
TitleScreen-Printable Contacts for Industrial N-TOPCon Crystalline Silicon Solar Cellsen_US
TypeArticleen_US
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