Mirror-plane disorder in a nickel chloride Schiff base com­plex: a suitable case study for crystallographic instruction

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dc.contributor.authorHsuan, Chang
dc.contributor.authorChen, Wen-Ching
dc.contributor.authorShen, Jiun-Shian
dc.contributor.authorOng, Tiow-Gan
dc.contributor.authorWang, Vincent C.-C.
dc.contributor.authorYap, Glenn P. A.
dc.date.accessioned2022-05-04T20:44:23Z
dc.date.available2022-05-04T20:44:23Z
dc.date.issued2022-01-27
dc.descriptionThis article was originally published in Acta Crystallographica Section C: Structural Chemistry. The version of record is available at: https://doi.org/10.1107/S2053229622000973en_US
dc.description.abstractThe nickel chloride complex of the Schiff base N2,N20-propanediylbis(2,3-butanedione-2-imine-3-oxime), namely, chlorido(3,9-dimethylundeca-3,8-diene-2,10-dione 10-oxime 2-oximato- 4N,N0,N00,N000)nickel(II), [NiCl(C 11 H19 N4 O2 )], at 100 K crystallizes in the orthorhombic space group Cmce. The structure exhibits mirror disorder of the main molecule that is not present in the bromide analogue. The relatively small number of unique reflections in the data set and the disorder imposed by the crystallographic mirror plane present a challenging educational case study.en_US
dc.description.sponsorshipFunding for this research was provided by: Ministry of Science and Technology, Taiwan (contract No. 110-2636-M-110-006 to VCCW).en_US
dc.identifier.citationChang, Hsuan, Wen-Ching Chen, Jiun-Shian Shen, Tiow-Gan Ong, Vincent C.-C. Wang, and Glenn P. A. Yap. “Mirror-Plane Disorder in a Nickel Chloride Schiff Base Complex: A Suitable Case Study for Crystallographic Instruction.” Acta Crystallographica Section C Structural Chemistry 78, no. 3 (March 1, 2022): 137–40. https://doi.org/10.1107/S2053229622000973.en_US
dc.identifier.issn2053-2296
dc.identifier.urihttps://udspace.udel.edu/handle/19716/30843
dc.language.isoen_USen_US
dc.publisherActa Crystallographica Section C: Structural Chemistryen_US
dc.subjectSchiff baseen_US
dc.subjectnickel complexen_US
dc.subjectcase studyen_US
dc.subjectdisorderen_US
dc.subjectoximeen_US
dc.subjectcrystal structureen_US
dc.titleMirror-plane disorder in a nickel chloride Schiff base com­plex: a suitable case study for crystallographic instructionen_US
dc.typeArticleen_US

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