Mechanism-based design of labile precursors for chromium(I) chemistry
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Royal Society of Chemistry
Abstract
Dinitrogen complexes of the type TpR,RCr–N2–CrTpR,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – TptBu,MeCr(g2-C2(SiMe3)2) – proved to be much more reactive.
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Final published version.
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Citation
Akturk, Eser S., Yap, Glenn P. A., Theopold,Klaus H.,. "Mechanism-Based Design of Labile Precursors for Chromium(i) Chemistry." Chem.Commun.Chem.Commun. 51.84 (2015): 15402-5. Print.