Synthesis and Crystal Structure of the Zintl Phases Na2CaCdSb2, Na2SrCdSb2 and Na2EuCdSb2

Simple item page
Author(s)Saparov, Bayram
Author(s)Bobev, Svilen
Date Accessioned2023-02-20T14:45:18Z
Date Available2023-02-20T14:45:18Z
Publication Date2022-12-18
DescriptionThis article was originally published in Inorganics. The version of record is available at: https://doi.org/10.3390/inorganics10120265
AbstractThis work details the synthesis and the crystal structures of the quaternary Zintl phases Na2CaCdSb2, Na2SrCdSb2 and Na2EuCdSb2. They are isostructural and their noncentrosymmetric structure is with the space group Pmc21 (Pearson code oP12). All structural work is carried out via single-crystal X-ray diffraction methods. The structure features [CdSb2]4– layers of corner-shared CdSb4 tetrahedra, which are stacked along the b-crystallographic axis and are separated by cations. The results from the structure refinements suggest that in addition to full cation ordering, which is typical for this structure, there also exists a possibility for an accommodation of a small degree of cation disorder.
SponsorThis research was funded by the US Department of Energy through a grant DE-SC0008885.
CitationSaparov, Bayram, and Svilen Bobev. 2022. "Synthesis and Crystal Structure of the Zintl Phases Na2CaCdSb2, Na2SrCdSb2 and Na2EuCdSb2" Inorganics 10, no. 12: 265. https://doi.org/10.3390/inorganics10120265
ISSN2304-6740
URLhttps://udspace.udel.edu/handle/19716/32330
Languageen_US
PublisherInorganics
Keywordsantimonides
Keywordscrystal structure
Keywordsthermoelectrics
KeywordsZintl phases
TitleSynthesis and Crystal Structure of the Zintl Phases Na2CaCdSb2, Na2SrCdSb2 and Na2EuCdSb2
TypeArticle
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Synthesis and Crystal Structure of the Zintl Phases.pdf
Size:
1.45 MB
Format:
Adobe Portable Document Format
Description:
Main article
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
2.22 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Open Access Publications