Controlled Synthesis of Pt Nanowires with Ordered Large Mesopores for Methanol Oxidation Reaction
| Author(s) | Zhang, Chengwei | |
| Author(s) | Xu, Lianbin | |
| Author(s) | Yan, Yushan | |
| Author(s) | Chen, Jianfeng | |
| Ordered Author | Chengwei Zhang, Lianbin Xu, Yushan Yan & Jianfeng Chen | |
| UD Author | Yan, Yushan | en_US |
| Date Accessioned | 2016-11-10T16:13:52Z | |
| Date Available | 2016-11-10T16:13:52Z | |
| Copyright Date | Copyright © The Author(s) 2016 | en_US |
| Publication Date | 2016-08-23 | |
| Description | Publisher's PDF | en_US |
| Abstract | Catalysts for methanol oxidation reaction (MOR) are at the heart of key green-energy fuel cell technology. Nanostructured Pt materials are the most popular and effective catalysts for MOR. Controlling the morphology and structure of Pt nanomaterials can provide opportunities to greatly increase their activity and stability. Ordered nanoporous Pt nanowires with controlled large mesopores (15, 30 and 45 nm) are facilely fabricated by chemical reduction deposition from dual templates using porous anodic aluminum oxide (AAO) membranes with silica nanospheres self-assembled in the channels. The prepared mesoporous Pt nanowires are highly active and stable electrocatalysts for MOR. The mesoporous Pt nanowires with 15 nm mesopores exhibit a large electrochemically active surface area (ECSA, 40.5 m2 g−1), a high mass activity (398 mA mg−1) and specific activity (0.98 mA cm−2), and a good If/Ib ratio (1.15), better than the other mesoporous Pt nanowires and the commercial Pt black catalyst. | en_US |
| Department | University of Delaware. Department of Chemical & Biomolecular Engineering. | en_US |
| Citation | Zhang, C. et al. Controlled Synthesis of Pt Nanowires with Ordered Large Mesopores for Methanol Oxidation Reaction. Sci. Rep. 6, 31440; doi: 10.1038/srep31440 (2016). | en_US |
| DOI | doi:10.1038/srep31440 | en_US |
| ISSN | 2045-2322 | en_US |
| URL | http://udspace.udel.edu/handle/19716/19833 | |
| Language | en_US | en_US |
| Publisher | Nature Publishing Group | en_US |
| dc.rights | This work is licensed under a Creative Commons Attribution 4.0 International License. | en_US |
| dc.source | Scientific Reports | en_US |
| dc.source.uri | http://www.nature.com/srep/ | en_US |
| Title | Controlled Synthesis of Pt Nanowires with Ordered Large Mesopores for Methanol Oxidation Reaction | en_US |
| Type | Article | en_US |
Files
License bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- license.txt
- Size:
- 2.22 KB
- Format:
- Item-specific license agreed upon to submission
- Description: