Scanning X-ray fluorescence spectroscopy and micro-X-ray absorption near-edge structure analysis as a guiding tool for the conservation treatment of two eighteenth-century Philadelphian portraits

Author(s)Porell, Mina
Author(s)Cushman, Matthew
Author(s)Fischel, Jason S. T.
Author(s)Fischel, Matthew H. H.
Author(s)Sparks, Donald L.
Author(s)Grayburn, Rosie
Date Accessioned2023-08-01T14:36:05Z
Date Available2023-08-01T14:36:05Z
Publication Date2023-04-02
DescriptionThis is the peer reviewed version of the following article: Porell, M., Cushman, M., Fischel, J. S. T., Fischel, M. H. H., Sparks, D. L., Grayburn, R., X-Ray Spectrom 2023, 1. https://doi.org/10.1002/xrs.3345, which has been published in final form at https://doi.org/10.1002/xrs.3345. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. © 2023 John Wiley & Sons Ltd. This article will be embargoed until 04/02/2024.
AbstractAn in-depth technical examination and conservation treatment of paintings by William Williams (Bristol 1727–1791 Bristol) has shed light on the artist's materials and technique. This investigation centered primarily on Williams's two 1766 portraits of William and David Hall. The paintings are considered the earliest life-sized, full-length portraits executed in the Philadelphia area. The analysis of the artist's palette indicated deliberate choices in the use of orpiment (As2S3). The mineral's tendency to oxidize to colorless and water-soluble arsenic oxides likely caused color changes and degraded organic binder in the orpiment-rich areas. μ-XANES revealed orpiment photodegradation to arsenate species at the paint surface, with migration to the ground layers. Just below the paint surface, arsenic remains bound primarily as arsenite, with some associated with sulfur as orpiment. This As distribution suggests that the paint is liable to further degradation by photooxidation and use of moisture would be detrimental. Given this treatment-critical degradation phenomenon, it was important to identify all arsenic-containing areas of both portraits. Scanning XRF allowed rapid and accurate collection of maps from both portraits. Elemental maps of arsenic identified the orpiment-rich areas of the painting, which would be susceptible to further degradation upon exposure to water during treatment. An aqueous adhesive was necessary to consolidate the cupped paint of the glue-paste lined paintings. The arsenic maps guided the use of two different consolidants–BEVA 371 for the water-sensitive orpiment-rich paint and sturgeon glue for all other areas, striking a compromise between esthetic improvement and long term preservation.
SponsorMany thanks to Mike Beauchaine (Bruker AXS) who facilitated the temporary loan of the M6 Jetstream to Winterthur. Thanks also to Rebecca Novetsky (formerly Bruker AXS) for training Winterthur staff on the M6 software and hardware. This research used the 4-BM (XFM) beamline of the National Synchrotron Light Source, a U.S. DOE Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory (BNL) under Contract No. DE-SC0012704. Advisory meetings, conservation treatment of the portraits of William Hall and David Hall, and early-career traineeships were funded through a grant from the Getty Foundation Conserving Canvas initiative. Funding for the synchrotron-based studies was provided by a grant from the University of Delaware Partnership for Arts and Culture (PAC).
CitationPorell, M., Cushman, M., Fischel, J. S. T., Fischel, M. H. H., Sparks, D. L., Grayburn, R., X-Ray Spectrom 2023, 1. https://doi.org/10.1002/xrs.3345
ISSN1097-4539
URLhttps://udspace.udel.edu/handle/19716/33043
Languageen_US
PublisherX-Ray Spectrometry
Keywordsarsenic speciation
Keywordspaintings conservation
Keywordsscanning XRF
Keywordsμ-XANES
TitleScanning X-ray fluorescence spectroscopy and micro-X-ray absorption near-edge structure analysis as a guiding tool for the conservation treatment of two eighteenth-century Philadelphian portraits
TypeArticle
Files
Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Scanning X-ray fluorescence spectroscopy.pdf
Size:
3.26 MB
Format:
Adobe Portable Document Format
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
2.22 KB
Format:
Item-specific license agreed upon to submission
Description: