Open Access Publications
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Open access publications by faculty, postdocs, and graduate students in the Department of Chemical and Biomolecular Engineering
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Browsing Open Access Publications by Subject "affordable and clean energy"
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Item Direct Integration of Strained-Pt Catalysts into Proton-Exchange-Membrane Fuel Cells with Atomic Layer Deposition(Advanced Materials, 2021-07-28) Xu, Shicheng; Wang, Zhaoxuan; Dull, Sam; Liu, Yunzhi; Lee, Dong Un; Pacheco, Juan S. Lezama; Orazov, Marat; Vullum, Per Erik; Dadlani, Anup Lal; Vinogradova, Olga; Schindler, Peter; Tam, Qizhan; Schladt, Thomas D.; Mueller, Jonathan E.; Kirsch, Sebastian; Huebner, Gerold; Higgins, Drew; Torgersen, Jan; Viswanathan, Venkatasubramanian; Jaramillo, Thomas Francisco; Prinz, Fritz B.The design and fabrication of lattice-strained platinum catalysts achieved by removing a soluble core from a platinum shell synthesized via atomic layer deposition, is reported. The remarkable catalytic performance for the oxygen reduction reaction (ORR), measured in both half-cell and full-cell configurations, is attributed to the observed lattice strain. By further optimizing the nanoparticle geometry and ionomer/carbon interactions, mass activity close to 0.8 A mgPt−1 @0.9 V iR-free is achievable in the membrane electrode assembly. Nevertheless, active catalysts with high ORR activity do not necessarily lead to high performance in the high-current-density (HCD) region. More attention shall be directed toward HCD performance for enabling high-power-density hydrogen fuel cells.Item Study of Cathode Gas Diffusion Architecture for Improved Oxygen Transport in Hydroxide Exchange Membrane Fuel Cells(Journal of The Electrochemical Society, 2022-05-04) Weiss, Catherine M.; Setzler, Brian P.; Yan, YushanThe high pH environment in hydroxide exchange membrane fuel cells (HEMFCs) has the potential to reach lower costs than the current proton exchange membrane fuel cells (PEMFCs), the incumbent technology. A significant difference between HEMFCs and PEMFCs is the location of water production within the cell. In PEMFCs, the water is produced on the cathode, limiting oxygen transport. In HEMFCs, the water is produced on the anode where the fuel is pure hydrogen. This allows the cathode to be optimized for oxygen transport without the presence of excess liquid water. Limiting current analysis, a technique previously used in PEMFCs, is adopted in HEMFCs to evaluate the oxygen mass transport resistances for different sections of the cathode. Through elimination of the microporous layer (MPL), gas diffusion layer (GDL), and traditional flow field and using porous nickel foam for gas distribution, the transport resistance at an operating condition of 150 kPa(g) and with the cell temperature at 80 °C was decreased from 112 s m−1 to 48 s m−1, effectively halved. The optimal configuration for performance was found with Ni foam and a GDL, eliminating the MPL and traditional flow field, which vastly improved oxygen transport while maintaining adequate electrical contact with the cathode catalyst layer.