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Browsing Center for Plastics Innovation by Subject "dielectric barrier discharge"
(ACS Sustainable Chemistry and Engineering, 2022-11-17) Nguyen, Darien K.; Dimitrakellis, Panagiotis; Talley, Michael R.; O'Dea, Robert M.; Epps, Thomas H. III; Watson, Mary P.; Vlachos, Dionisios G.
We introduce the oxidation of long aliphatic alkanes using non-thermal, atmospheric plasma processing as an eco-friendly route for organic synthesis. A pulsed dielectric barrier discharge in He/O2 gas mixtures was employed to functionalize n-octadecane. C18 secondary alcohols and ketones were the main products, with an optimal molar yield of ∼29.2%. Prolonged treatment resulted in the formation of dialcohols, diketones, and higher molecular weight oxygenates. Lighter hydrocarbon products and decarboxylation to CO2 were also observed at longer treatment times and higher power inputs. A maximum energy yield of 5.48 × 10–8 mol/J was achieved at short treatment times and high powers, associated with higher selectivity to primary oxygenates. Direct hydroxylation of alkyl radicals, as well as disproportionation reactions, are proposed as the main pathways to alcohols and ketones. The results hold promise for functionalizing long hydrocarbon molecules at ambient conditions using catalyst-free plasma discharges.