Browsing by Author "Vermant, Jan"
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Item Advective Assembler-Enhanced Support Bath Rotational Direct Ink Writing(Advanced Materials Technologies, 2024-05-01) Pleij, Tazio; Bayles, Alexandra V.; Vermant, JanManufacturing intricately controlled, hierarchically distributed structures poses significant fabrication challenges, but is crucial for enhancing functionality in synthetic systems. A 3D printing technique combining advective assembly with rotational direct ink writing is developed and exploited to build topologically complex, multimaterial structures with high precision. A modular advective assembler printhead is fabricated and employed in the process. This flow-structuring device is designed with a complex network of internal channels that patterns flowing hydrogel-based inks, creating multi-layered filaments whose structures go well beyond conventional nozzle shape and size limitations. The composite filaments are extruded into a rotating support bath of Polyacrylic acid microgels. The rheology of the inks and support bath are critical to maintain print fidelity and integrity, and are characterized by linear and nonlinear bulk rheometry. Optimization of the materials creates a platform where curvilinear, multimaterial architectures are constructed without being constrained to slicing across X, Y, and Z axes. The versatility of this manufacturing platform is demonstrated by printing helical structures that undergo swelling-induced actuation. This processing method has the potential to significantly enhance additive manufacturing by enabling the production of intricate, multiscale composite structures with broad applicability in fields such as bioengineering, soft robotics, and functional composite materials.Item Polysiloxane Inks for Multimaterial 3d Printing of High-Permittivity Dielectric Elastomers(Advanced Functional Materials, 2023-12-27) Danner, Patrick M.; Pleij, Tazio; Siqueira, Gilberto; Bayles, Alexandra V.; Venkatesan, Thulasinath Raman; Vermant, Jan; Opris, Dorina M.Dielectric elastomer transducers (DET) are promising candidates for electrically-driven soft robotics. However, the high viscosity and low yield stress of DET formulations prohibit 3D printing, the most common manufacturing method for designer soft actuators. DET inks optimized for direct ink writing (DIW) produce elastomers with high stiffness and mechanical losses, diminishing the utility of DET actuators. To address the antagonistic nature of processing and performance constraints, principles of capillary suspensions are used to engineer DIW DET inks. By blending two immiscible polysiloxane liquids with a filler, a capillary ink suspension is obtained, in which the ink rheology can be tuned independently of the elastomer electromechanical properties. Rheometry is performed to measure and optimize processibility as a function of filler and secondary liquid fraction. Including polar polysiloxanes as the secondary liquid produces a printed elastomer exhibiting a four-fold permittivity increase over commercial polydimethylsiloxane. The characterization and multimaterial printing into layered DET devices demonstrates that the immiscible capillary suspension improves the processability of the inks and enhances the properties of the elastomers, enabling actuation of the devices at comparatively low voltages. It is anticipated that this formulation approach will allow soft robotics to harness the full potential of DETs.