Mechanism-based design of labile precursors for chromium(I) chemistry
| Author(s) | Akturk, Eser S. | |
| Author(s) | Yap, Glenn P. A. | |
| Author(s) | Theopold, Klaus H. | |
| Ordered Author | Eser S. Akturk, Glenn P. A. Yap and Klaus H. Theopold | |
| UD Author | Akturk, Eser Sahin | en_US |
| UD Author | Yap, Glenn P. A. | en_US |
| UD Author | Theopold, Klaus H. | en_US |
| Date Accessioned | 2015-11-19T14:41:16Z | |
| Date Available | 2015-11-19T14:41:16Z | |
| Copyright Date | Copyright ©2015 Royal Society of Chemistry | en_US |
| Publication Date | 2015-08-27 | |
| Description | Final published version. | en_US |
| Abstract | Dinitrogen complexes of the type TpR,RCr–N2–CrTpR,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – TptBu,MeCr(g2-C2(SiMe3)2) – proved to be much more reactive. | en_US |
| Department | University of Delaware. Department of Chemistry and Biochemistry. | en_US |
| Citation | Akturk, Eser S., Yap, Glenn P. A., Theopold,Klaus H.,. "Mechanism-Based Design of Labile Precursors for Chromium(i) Chemistry." Chem.Commun.Chem.Commun. 51.84 (2015): 15402-5. Print. | en_US |
| DOI | 10.1039/c5cc05993c | en_US |
| ISSN | 1359-7345 ; e:1364-548X | en_US |
| URL | http://udspace.udel.edu/handle/19716/17236 | |
| Language | en_US | en_US |
| Publisher | Royal Society of Chemistry | en_US |
| dc.rights | Article is made available in accordance with the University of Delaware Faculty Policy on Open Access and the publisher's policy. | en_US |
| dc.rights | CC-BY 3.0 Klaus Theopold | |
| dc.source | ChemComm | en_US |
| dc.source.uri | http://www.rsc.org/journals-books-databases/about-journals/chemcomm/ | en_US |
| Title | Mechanism-based design of labile precursors for chromium(I) chemistry | en_US |
| Type | Article | en_US |