Engineering lignin-derivable diacrylate networks with tunable architecture and mechanics
Date
2024-07-03
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Materials Advances
Abstract
Network engineering strategies offer a promising pathway toward tunable thermomechanical properties of bio-derivable, aromatic (meth)acrylate thermosets to expand their application library. In this work, a series of acrylate thermosets, synthesized from lignin-derivable vanillyl alcohol/bisguaiacol F diacrylates (VDA/BGFDA) and a bio-based n-butyl acrylate (BA), were designed as a sustainable platform to explore structure-architecture-property relationships. Using this approach, we examined a series of processable, fully bio-derivable acrylates. Increasing the diacrylate content across all networks improved storage moduli at 25 °C (E′25) by up to 2 GPa (1.1 GPa for VDA/BA-25/75 vs. 3.1 GPa for VDA/BA-75/25, and 1.5 GPa for BGFDA/BA-25/75 vs. 1.7 GPa for BGFDA/BA-50/50), and led to a more inhomogeneous network as evidenced by lower acrylate group conversion and a broader tan δ peak, indicating heterogeneous relaxation modes. Modifying the aromatic content of the starting diacrylate impacted the final inhomogeneity of the network, with increasing inhomogeneity observed for the bis-aromatic BGFDA relative to the mono-aromatic VDA. Similarly, combining the mono- and bis-aromatic diacrylates generated a network with a biphasic-like thermal relaxation mode. By correlating network architecture and material performance, the increasing architectural complexity suggested a more convoluted thermal relaxation mode while the enhancement of thermomechanical properties could still be achieved for potential application as damping materials. Overall, we presented a design strategy utilizing bio-derivable acrylates to expand the suite of renewable material platforms from a network engineering perspective.
Description
This article was originally published in Materials Advances. The version of record is available at: https://doi.org/10.1039/D4MA00159A. © 2024 The Author(s). Published by the Royal Society of Chemistry
Keywords
industry, innovation, and infrastructure, responsible consumption and production
Citation
Wong, Yu-Tai, and LaShanda T. J. Korley. “Engineering Lignin-Derivable Diacrylate Networks with Tunable Architecture and Mechanics.” Materials Advances 5, no. 15 (2024): 6070–80. https://doi.org/10.1039/D4MA00159A.