Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction
| Author(s) | Crandall, Bradie S. | |
| Author(s) | Qi, Zhen | |
| Author(s) | Foucher, Alexandre C. | |
| Author(s) | Weitzner, Stephen E. | |
| Author(s) | Akhade, Sneha A. | |
| Author(s) | Liu, Xin | |
| Author(s) | Kashi, Ajay R. | |
| Author(s) | Buckley, Aya K. | |
| Author(s) | Ma, Sichao | |
| Author(s) | Stach, Eric A. | |
| Author(s) | Varley, Joel B. | |
| Author(s) | Jiao, Feng | |
| Author(s) | Biener, Juergen | |
| Date Accessioned | 2024-08-28T14:27:08Z | |
| Date Available | 2024-08-28T14:27:08Z | |
| Publication Date | 2024-07-12 | |
| Description | This is the peer reviewed version of the following article: B. S. Crandall, Z. Qi, A. C. Foucher, S. E. Weitzner, S. A. Akhade, X. Liu, A. R. Kashi, A. K. Buckley, S. Ma, E. A. Stach, J. B. Varley, F. Jiao, J. Biener, Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction. Small 2024, 2401656. https://doi.org/10.1002/smll.202401656, which has been published in final form at https://doi.org/10.1002/smll.202401656. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. © 2024 Wiley-VCH GmbH. This article will be embargoed until 07/12/2025. | |
| Abstract | Electrochemical CO2 reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in catalyst selectivity need to be made. So far, only copper-based catalysts have shown efficient conversion of CO2 into the desired multi-carbon (C2+) products. This work explores Cu-based dilute alloys to systematically tune the energy landscape of CO2 electrolysis toward C2+ products. Selection of the dilute alloy components is guided by grand canonical density functional theory simulations using the calculated binding energies of the reaction intermediates CO*, CHO*, and OCCO* dimer as descriptors for the selectivity toward C2+ products. A physical vapor deposition catalyst testing platform is employed to isolate the effect of alloy composition on the C2+/C1 product branching ratio without interference from catalyst morphology or catalyst integration. Six dilute alloy catalysts are prepared and tested with respect to their C2+/C1 product ratio using different electrolyzer environments including selected tests in a 100-cm2 electrolyzer. Consistent with theory, CuAl, CuB, CuGa and especially CuSc show increased selectivity toward C2+ products by making CO dimerization energetically more favorable on the dominant Cu facets, demonstrating the power of using the dilute alloy approach to tune the selectivity of CO2 electrolysis. | |
| Sponsor | IM release number: LLNL-JRNL-860893. B.S.C. and Z.Q. equally contributed to this work. This work was supported by the US Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE) under the Advanced Manufacturing Office Next Generation R&D Projects award number DE-EE-0008327. The views expressed herein do not necessarily represent the views of the US Department of Energy or the United States Government. The work was performed under the auspices of the US Department of Energy by LLNL under contract No. DE-AC52-07NA27344 and a Strategic Partnership Program agreement with TOTAL American Services, Inc. (affiliate of TOTAL SE) under contract No. L-21350. [Correction added on July 18, 2024, after first online publication: Figure 6 was updated.] | |
| Citation | B. S. Crandall, Z. Qi, A. C. Foucher, S. E. Weitzner, S. A. Akhade, X. Liu, A. R. Kashi, A. K. Buckley, S. Ma, E. A. Stach, J. B. Varley, F. Jiao, J. Biener, Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction. Small 2024, 2401656. https://doi.org/10.1002/smll.202401656 | |
| DOI | affordable and clean energy | |
| ISSN | 1613-6829 | |
| URL | https://udspace.udel.edu/handle/19716/34898 | |
| Language | en_US | |
| Publisher | Small | |
| Keywords | alloy | |
| Keywords | catalyst morphology | |
| Keywords | copper catalyst | |
| Keywords | density functional theory | |
| Keywords | electrochemical CO2 reduction | |
| Keywords | energy efficiency | |
| Keywords | physical vapor deposition | |
| Keywords | climate action | |
| Title | Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction | |
| Type | Article |
Files
Original bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction.pdf
- Size:
- 1.82 MB
- Format:
- Adobe Portable Document Format
- Description:
- Main article
License bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- license.txt
- Size:
- 2.22 KB
- Format:
- Item-specific license agreed upon to submission
- Description: