Effects of Chitin Nano-flake Fillers on the Mechanical and Barrier Properties of Polylactic Acid Biocomposite Films

Abstract

Polylactic acid (PLA) is a biodegradable polymer extensively used in packaging; however, its mechanical and barrier properties require enhancement for wider applications. Chitin-derived nanoflakes (CNFL), a two-dimensionally separated nanomaterial derived from α-chitin, possess high strength and toughness, making them ideal additives for improved PLA performance. This study investigated the effect of CNFL on the properties of PLA composite films. Incorporating CNFL significantly enhanced the mechanical properties of PLA, increasing its tensile strength and stiffness while preserving flexibility. This enhancement was attributed to the nucleating effect of CNFL, which increases crystallinity. Additionally, CNFL improved the thermal stability of the composite films by mitigating thermal deformation. Notably, the oxygen barrier properties of CNFL-filled PLA composites were also enhanced, demonstrating a significant reduction in oxygen permeability at optimal CNFL concentrations due to increased tortuosity of the oxygen diffusion path. Overall, CNFL-filled PLA composites exhibit great potential as renewable packaging materials, particularly for protecting sensitive products, such as food and pharmaceuticals, from oxidative degradation, thereby extending shelf life and maintaining quality. These findings suggest that CNFL-filled PLA composites are promising materials for advanced applications, offering a combination of enhanced mechanical performance, improved thermal stability, and superior oxygen barrier properties.