Post-synthetic modification of amine-functionalized permanently porous coordination cages
Author(s) | Hoq, Jahidul | |
Author(s) | Dworzak, Michael R. | |
Author(s) | Dissanayake, Duleeka | |
Author(s) | Skalla, Rebecca X. | |
Author(s) | Yamamoto, Nobuyuki | |
Author(s) | Yap, Glenn P. A. | |
Author(s) | Bloch, Eric D. | |
Date Accessioned | 2025-02-04T19:38:19Z | |
Date Available | 2025-02-04T19:38:19Z | |
Publication Date | 2024-12-04 | |
Description | This article was originally published in Chemical Communications. The version of record is available at: https://doi.org/10.1039/D4CC04370G. This journal is © The Royal Society of Chemistry 2025. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/). | |
Abstract | This manuscript explores the post-synthetic modification (PSM) of amine-functionalized porous coordination cages, specifically focusing on the formation of imine bonds through reactions with aldehydes. Targeting various cage topologies, including zirconium-, magnesium-, and molybdenum-based structures, we demonstrate the tunability of cage solubility and porosity through selective functionalization where the proximity of amine groups on the parent cage impacts the extent of modification. The work highlights the reversible nature of imine formation, offering potential applications in solubility switching and mixed-metal solid synthesis. | |
Sponsor | The authors gratefully acknowledge financial support from the National Science Foundation (2154976) and Indiana University. Support for the acquisition of the Bruker Venture D8 diffractometer through the Major Scientific Research Equipment Fund from the President of Indiana University and the Office of the Vice President for Research is gratefully acknowledged. GPAY thanks the National institutes of Health for grant S10 OD026896A. | |
Citation | Hoq, Jahidul, Michael R. Dworzak, Duleeka Dissanayake, Rebecca X. Skalla, Nobuyuki Yamamoto, Glenn P. A. Yap, and Eric D. Bloch. “Post-Synthetic Modification of Amine-Functionalized Permanently Porous Coordination Cages.” Chemical Communications 61, no. 8 (2025): 1641–44. https://doi.org/10.1039/D4CC04370G. | |
ISSN | 1364-548X | |
URL | https://udspace.udel.edu/handle/19716/35789 | |
Language | en_US | |
Publisher | Chemical Communications | |
dc.rights | Attribution 3.0 Unported | en |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/ | |
Title | Post-synthetic modification of amine-functionalized permanently porous coordination cages | |
Type | Article |
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