Mechanism-based design of labile precursors for chromium(I) chemistry

Date
2015-08-27
Authors
Akturk, Eser S.
Yap, Glenn P. A.
Theopold, Klaus H.
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Dinitrogen complexes of the type TpR,RCr–N2–CrTpR,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – TptBu,MeCr(g2-C2(SiMe3)2) – proved to be much more reactive.
Description
Final published version.
Keywords
Citation
Akturk, Eser S., Yap, Glenn P. A., Theopold,Klaus H.,. "Mechanism-Based Design of Labile Precursors for Chromium(i) Chemistry." Chem.Commun.Chem.Commun. 51.84 (2015): 15402-5. Print.